Cyclopentadienyl-silsesquioxane titanium complexes: highly active catalysts for epoxidation of alkenes with aqueous hydrogen peroxide.
نویسندگان
چکیده
Titanium complexes bearing an unprecedented tridentate cyclopentadienyl-silsesquioxanate ligand provide a new class of efficient and selective catalysts for epoxidation of olefins with aqueous hydrogen peroxide under homogeneous conditions.
منابع مشابه
An efficient hybrid, nanostructured, epoxidation catalyst: titanium silsesquioxane-polystyrene copolymer supported on SBA-15.
A novel interfacial hybrid epoxidation catalyst was designed with a new immobilization method for homogeneous catalysts by coating an inorganic support with an organic polymer film containing active sites. The titanium silsesquioxane (TiPOSS) complex, which contains a single-site titanium active center, was immobilized successfully by in-situ copolymerization on a mesoporous SBA-15-supported po...
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ورودعنوان ژورنال:
- Inorganic chemistry
دوره 51 11 شماره
صفحات -
تاریخ انتشار 2012